Ecotoxicological evaluation of dredged sediments from Rodrigo de Freitas Lagoon (Rio de Janeiro State,Brazil) using bioassays with earthworms and collembolans

The toxicity and metal bioavailability were studied in dredged sediments from Rodrigo de Freitas Lagoon (Rio de Janeiro, RJ, Brazil) using acute and avoidance tests with Eisenia andrei, and reproduction tests with Folsomia candida. The sediment was mixed with an artificial soil, and two natural soils (ferralsol and chernosol—representative Brazilian tropical soils) to obtain the following doses: 1, 3, 6, 12, 18, 24 and 30%. Total metal concentrations were determined in the sediment to support the interpretation of ecotoxicological data. Metal concentrations in the mixtures were in agreement with the threshold limits established by Brazilian law. However, significant avoidance responses were found on doses ≥?3% and were the most sensitive endpoint. Earthworm mortality found in artificial soil mixtures (LC50?=?3.9) suggests higher toxicity levels than those obtained in ferralsol (LC50?=?7.6%) and chernosol (11.0%) treatments. Earthworm mortality, avoidance responses and collembolan reproduction levels found in ferralsol mixtures (LC50?=?9.2; avoidance EC50?=?2.3%; reproduction EC50?=?2.8%) were higher compared to chernosol treatments (LC50?=?11.0%; avoidance EC50?=?4.3%; reproduction EC50?=?4.9%). The reduction of toxicity levels in chernosol mixtures is probably due to the abundance of expansive clay minerals in chernosols with capacity of adsorbing metals and other xenobiotic substances from soil pore water, decreasing metal bioavailability. Finally, threshold limits defined by Brazilian legislation for soil quality and land disposal of dredged sediments are not sufficient to prevent noxious effects on soil fauna and should be complemented with a preliminary ecotoxicological evaluation.     

Spectral data source effect on crop state estimation by vegetation indices

Spectral vegetation indices (VIs) are a well-known and widely used method for crop state estimation. The ability to monitor crop state by such indices is an important tool for agricultural management. Even though differences in imagery and point-based spectroscopy are obvious, their impact on crop state estimation by VIs is not well-studied. The aim of this study was to assess the performance level of the selected VIs calculated from spaceborne multispectral imagery and point-based field spectroscopy in application to crop state estimation. For this purpose, irrigated chickpea field was monitored by RapidEye satellite mission and additional measurements by field spectrometer were obtained. Estimated VIs average and coefficient of variation from each observation were compared with physical crop measurements: leaf water content, LAI and chlorophyll level. The results indicate that indices calculated from spaceborne spectral images regardless of the claimed response commonly react on phenology of the irrigated chickpea. This feature makes spaceborne spectral imagery an appropriate data source for monitoring crop development, crop water needs and yield prediction. VIs calculated from field spectrometer were sensitive for estimating pigment concentration and photosynthesis rate. Yet, a hypersensitivity of field spectral measures might lead to a very high variability (up to 69%) of the calculated values. Consequently, the high spatial variability of field spectral measurements depreciates the estimation agricultural field state by average mean only. Nevertheless, the spatial variability might have certain behavior trend, e.g., a significant increase in the active growth or stress and can be an independent feature for field state assessment.     

Hydrologic models coupled with 2D hydrodynamic model for high-resolution urban flood simulation

Natural Hazards - Floods are the most frequent natural disaster and pose a very challenging threat to many cities worldwide. Understanding the flood dynamic is essential for developing strategies...     

Methodological challenges to confirmatory latent variable models of social vulnerability

Natural Hazards - Socially vulnerable communities experience disproportionately negative outcomes following natural disasters and underscoring a need for well-validated measures to identify those...     

Testing the consistency of Holocene and Last Glacial Maximum spatial correlations in temperature proxy records

Holocene temperature proxy records are commonly used in quantitative synthesis and model-data comparisons. However, comparing correlations between time series from records collected in proximity to one another with the expected correlations based on climate model simulations indicates either regional or noisy climate signals in Holocene temperature proxy records. In this study, we evaluate the consistency of spatial correlations present in Holocene proxy records with those found in data from the Last Glacial Maximum (LGM). Specifically, we predict correlations expected in LGM proxy records if the only difference to Holocene correlations would be due to more time uncertainty and more climate variability in the LGM. We compare this simple prediction to the actual correlation structure in the LGM proxy records. We found that time series data of ice-core stable isotope records and planktonic foraminifera Mg/Ca ratios were consistent between the Holocene and LGM periods, while time series of Uk'37 proxy records were not as we found no correlation between nearby LGM records. Our results support the finding of highly regional or noisy marine proxy records in the compilation analysed here and suggest the need for further studies on the role of climate proxies and the processes of climate signal recording and preservation.     

A novel methodological approach for land subsidence prediction through data assimilation techniques

Computational Geosciences - Anthropogenic land subsidence can be evaluated and predicted by numerical models, which are often built over deterministic analyses. However, uncertainties and...     

What drives policy change for REDD+? A qualitative comparative analysis of the interplay between institutional and policy arena factors

Reducing Emissions from Deforestation and forest Degradation (REDD+) has emerged as a promising climate change mitigation mechanism in developing countries. In order to identify the enabling conditions for achieving progress in the implementation of an effective, efficient and equitable REDD+, this paper examines national policy settings in a comparative analysis across 13 countries with a focus on both institutional context and the actual setting of the policy arena. The evaluation of REDD+ revealed that countries across Africa, Asia and Latin America are showing some progress, but some face backlashes in realizing the necessary transformational change to tackle deforestation and forest degradation. A Qualitative Comparative Analysis (QCA) undertaken as part of the research project showed two enabling institutional configurations facilitating progress: (1) the presence of already initiated policy change; and (2) scarcity of forest resources combined with an absence of any effective forestry framework and policies. When these were analysed alongside policy arena conditions, the paper finds that the presence of powerful transformational coalitions combined with strong ownership and leadership, and performance-based funding, can both work as a strong incentive for achieving REDD+ goals.

Key policy insights

• The positive push of already existing policy change, or the negative stress of resource scarcity together with lack of effective policies, represents institutional conditions that can support REDD+ progress.

• Progress also requires the presence of powerful transformational coalitions and strong ownership and leadership. In the absence of these internal drivers, performance-based funding can work as a strong incentive.

• When comparing three assessments (2012, 2014, 2016) of REDD+ enabling conditions, some progress in establishing processes of change can be observed over time; however, the overall fluctuation in progress of most countries reveals the difficulty in changing the deforestation trajectory away from business as usual.

     

A well‐established Early–Middle Pleistocene marine sequence on south‐east Zakynthos island,western Greece: Magneto‐biostratigraphic constraints and palaeoclimatic implications

The chronostratigraphy of a long, onshore Early–Middle Pleistocene marine sedimentary sequence on the south‐east part of Zakynthos island, Greece, is presented. Correlation of the succession with the isotope record of Ocean Drilling Program Site 963 reveals the combined influence of tectonics and eustacy in this area. The sequence is divided into three formations by two main unconformities that apparently relate to sea‐level lowstands associated with two major northern hemisphere glaciations, those of marine isotope stages (MIS) 22 and 12. The Zakynthos sequence in many ways is comparable with the Italian Valle di Manche section. Magnetostratigraphic and rock magnetic analyses, supported by biostratigraphy, document the position of the Matuyama/Brunhes Chron boundary (0.77 Ma), the top and base of the Jaramillo Subchron (0.99–1.07 Ma), the Cobb Mountain Subchron (1.173–1.185 Ma) and the top of the Olduvai Subchron (1.78 Ma). The underlying strata are constrained exclusively by detailed nannofossil biostratigraphy extending at least to the lowermost Pleistocene at around 2.54 Ma and therefore certainly incorporating the base of the Olduvai Subchron (1.95 Ma) and possibly the Gauss/Matuyama Chron boundary (2.58 Ma). In addition, a remarkable increase in sedimentation rate (from 3.2 and 28 cm ka^?1 to 167 cm ka^?1) and hence resolution above the Matuyama/Brunhes boundary (Middle Pleistocene) reveals one short‐lived magnetic excursion, possibly 17a (0.66 Ma), within the normal polarity Brunhes Chron. Copyright © 2011 John Wiley & Sons, Ltd.     

Mass transport triggered by heavy rainfall: the role of endorheic basins and epikarst in a regional karst aquifer

This study aims at recognizing the mechanisms of mass transport between the karst surface and the saturated zone in a morphostructural relief of the Mesozoic karst carbonate platform of Murgia (Puglia, Southern Italy). The large dimension of the karst aquifer, the regional scale of the flow system, the boundary condition constituted by the sea, and the lack of freshwater springs constrain to the use of wells as monitoring points and limit the study area to the recharge area comprising 986 endorheic basins. The concentrations of non‐reactive tracers (nitrates) in the waters of autogenic recharge (from endorheic basins) have been modeled through the evaluation of effective infiltration, land use, and nitrogen surplus, with reference to a time window, which includes a low precipitation period followed by significant rainfall events. The comparison between the modeled nitrate concentrations and the nitrate concentrations measured in ground waters, coupled with the analysis of groundwater chemograms and records of hydraulic heads (all referred to the same time window), allows inferring the mechanism of mass transport between the karst surface and the groundwater table. The mass transport conceptual model requires the presence of the epikarst. The infiltration of significant rainfall in the endorheic basins after a low precipitation period displaces waters stored in the epikarst toward the saturated zone. Ground waters in the post‐event period show higher concentrations of nitrates, lower concentrations of total organic carbon, and higher Mg/Ca ratios than both those of the pre‐event period and the autumn‐winter recharge period. The post‐event recharge from epikarst storage determines a transient hazard of groundwater pollution with a time lag from the occurrence of the heavy rainfall.